If you bought a new built property and have copy of your lease, your freeholder will be named on the lease.
Otherwise, if you receive ground rent demands, the name and the address of the freeholder should be on the demand. If the freeholder manages the property himself, his name and address should be on every service charge demand he may send to demand the charges.
Finally you can contact the Land Registry to find out who the registered freeholder is and if necessary obtain a copy of the freehold title register.
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